SDS_2016_Duralay_Powder_Red

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5. 5 of 5 Duralay Powder Red RISK STATEMENTS: R36/37/38 – Irritating to eyes, respiratory system and skin. SAFETY STATEMENTS: S3 – Keep in a cool place. S7 – Keep container tightly closed. S9 – Keep container in a well - ventilated place. S20 – When using do not eat or drink. S 29 – Do not empty into drains. S37/39 – Wear suitable gloves and eye/face protection. Section 16 - Additional Information HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles. NATIONAL FIRE PROT ECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 ABBREVIATIONS: NA: Not Applicable ND: Not Determined NE: Not Established ppm: parts per million G: Gallon mg: Milligram L: Lit er gm: Gram mol: Mole kg: Kilogram μ: Micro mm: Millimeter p Pico Pa: Pascals LC: Lethal Concentration LD: Lethal Dose TC: Toxic Concentration TD: Toxic Dose BOD: Biological Oxygen Demand COD: Chemical Oxygen Demand Lo: Lowest ThOD: Theoretical Oxygen Demand Tlm: Threshold Limit H: Hours M: Months D: Days Y: Years W: Weeks ACGIH: American Conference of Governmental Industrial Hygienist CPR: Controlled Product’s Regulation DSL: Canadian Domestic Substances List NDSL: C anadian Non - domestic Substance List IARC: International Agency for Research for Cancer NOEL: No Observed Effect Level NOAEL: No Observed Adverse Effect Level OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit TLV: Thre shold Limit Value THIS MATERIAL SAFETY DATA SHEET IS PREPARED IN COMPLIANCE WITH FEDERAL REGULATIONS (29 CFR 1910.1200), THE COMMONWEALTH OF PENNSYLVANIA REGULATIONS (TITLE 34. CHAPTERS 301 - 323) AND CANADIAN WHMIS REGULATIONS, ANY APPLICABLE STATE AND LOCAL REGULATIONS SHOULD BE CONSULTED. THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION, WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON T HE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE THEREOF. Revised April 4, 2016

2. 2 of 5 Duralay Powder Red Section 4 - First Aid Measures EMERGENCY AND FIRST AID PROCEDURES: EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at least 15 minutes. If irritation occurs, contact a physician. INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or milk. Never give anything by mouth to an unconscious person. Provide an estimate of the time at which the material was ingested and the amount of the substance that was swallowed. Get medical attention immediately. INHALATION: Remove to fresh air. Seek immediate medical attention. SKIN: If irritation occurs and product is on the skin , rinse thoroughly with lukewarm water, followed by a thorough washing of the effected area with soap and water. If irritation, redness or swelling persists, contact a physician immediately. CLOTHING: Remove contaminated clothing, wash thoroughly before reuse. TREATMENT: Treat symptoms conventionally, after thorough decontamination. Section 5 - Fire Fighting Measures ON 5 - FIRE FIGHTING MEASURES FLASH POINT: 304  C, 580  F FLAMMABLE LIMIT , AIR VOL% LOWER: NA UPPER: NA AUTOIGNITION TEMPERATURE: NE EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical. FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer particles suspended in air are approximately those of coal dust . SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds. Water stream can disperse dust into air producing a fire hazard and possible explosion hazard if exposed to ignition source. EXPLOSION HAZARD: Firefighters should wear self - contained breathing apparatus. SENSITIVE TO MECHANICAL IMPACT: For Polymer: No. SENSITIVE TO STATIC DISCHARGE: For Polymer: No. Section 6 - Accidental Release Measures ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear appropriate Personal Protective Equipment (e.g., goggles, gloves). Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning up spills. Dis pose of properly in accordance with local, state and federal regulations. Wash all affected areas with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before reuse. E Section 7 - Handling and Storage PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and clothing. Avoid breathing dust. Use good personal hygiene and housekeeping. PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight, other l light sources, or sources of intense heat. Keep container closed to prevent water absorption and contamination. INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well - ventilated l ocation (e.g., local exhaust ventilation, fans). After use, wash hands and exposed skin with soap and water. Do not eat, drink or smoke while handling product.

4. 4 of 5 Duralay Powder Red Section 11 - Toxicological Information TOXICITY DATA: This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the components of the product, which is found in scientific literature. This data has not been presented in this document. MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans. REPRODUCTIVE TOXICITY DATA: Embryotoxicity: This product is not reported to produce embryotoxic effects in humans. Teratogenicity: This product is not reported to cause teratogenic effects in humans. Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. Section 12 - Ecological Information AQUATIC TOXICITY: There is no specific data available for this product; however, very large releases of this product may be harmful or fatal to overexposed aquatic life. ENVIRONMENTAL FATE: There is no specific data available for this product. Section 13 - Disposal C onsiderations WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local regulations. DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended. Employees should be advised of the potential ha zards due to residual material associated with empty containers. Dispose of all empty containers properly in accordance with Federal, State and Local regulations. Section 14 - Transport Information DOT/UN SHIPPING NAME: POLYMER, NOI DOT/UN CLASS: NA/UN NUMBER: PACKING GROUP: LABEL: IMDG CLASS: IMDG PG: CERCLA RQ: Section 15 - Regulatory Information SARA Reporting Requirements: Yes SARA Threshold Planning Quantity: There may be specific Threshold Planning Quantities for the components of this product. TSCA Inventory Status: The components of this product are listed on the TSCA Inventory. For use in FDA regulated products only. CERCLA Reportable Quantity (RQ): NA Other Federal Requirements: This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics). Other Canadian Regulations: This product has been classified according to the hazar d criteria of the CPR and the MSDS contains all of the information required by the CPR. The components of this product are listed on the DSL/NDSL. None of the components of this product are listed on the Priorities Substances List. State Regulatory Information: This product may contain components that are covered under specific state criteria.

1. 1 of 5 Duralay Powder Red Safety Data Sheet Section 1 - Chemical Product and Company Identification Product Name: Duralay Powder Red Company Identification: Reliance Dental Mfg., LLC. 5805 W. 117 th Place Alsip, IL 60803 For Product Information, call: 708 - 597 - 6694 For Medical Information, call: 800 - 535 - 5053 Section 2 - Hazards Identification EMERGENCY OVERVIEW: WARNING: For Polymer: OSHA classifies this material as Particulates, Not Otherwise Classified. Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no matter how generated. Symptoms of overexposure may include redness, itching, irritation, burning pain and watering. Keep dust out of eyes. Ingestion: Not expected to cause any harmful effects. Ingestion of large amounts may be irritating if product is swallowed, may cause nausea, headache, vomiting and/or diarrhea. Skin: May be irritating to skin in some sensitive individuals, especially after prolonged and/or rep eated contact. Prolonged or repeated contact may cause redness and burning. Inhalation: May be irritated by gross overexposure, no matter how generated. Vapors or mists may cause irritation the respiratory tract, nausea, central nervous sys tem depression such as drowsiness, dizziness, loss of coordination and fatigue. Chronic Hazards: None known. For Diethyl Phthalate: Chronic Hazards: Inhalation: Persons with impaired lung function or asthma - like conditions may experience additional breathing difficulties. Reproductive: Possible teratogen. Skin: Prolonged or repeated contact may cause redness, burning, drying, cracking and dermatitis. Persons with pre - existing skin disorders may be more susceptible to this material. CARCINOGENICITY: IARC lists Benzoyl Peroxide as unclassifiable as to carcinogenicity to humans. None of the other components of this material are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. PRIMARY ROUTES OF ENTRY: I nhalation, Skin or Eyes. Section 3 - Composition, Information on Ingredients Item Chemical Name CAS # WT/WT% 01 Polymer 9011 - 14 - 7 60.0 - 100.0 02 Diethyl Phthalate 84 - 66 - 2 0.0 - 20.0 03 Benzoyl Peroxide 94 - 36 - 0 0.0 - 10.0 ACGIH OSHA Company ITEM TLV - TWA TLV - STEL PEL TWA PEL CEILING Recommendation SKIN 01 10 mg/m 3 NE 15 mg/m 3 NE 15 mg/m 3 NE 02 5 mg/m 3 NE 5 mg/m 3 NE 5 mg/m 3 NE 03 5 mg/m 3 NE 5 mg/m 3 NE 5 mg/m 3 NE SECTION 4 - FIRST AID RE S

3. 3 of 5 Duralay Powder Red Section 8 - Exposure Controls, Personal Protection VENTILATION: When work ing with large quantities of product provide adequate ventilation (e.g., local exhaust ventilation, fans). Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes. Use good local exhaust at processing e quipment, including buffers, sanders, grinders and polishers. RESPIRATORY PROTECTION: No special respiratory protection is required under typical circumstances of use or handling. If necessary, use only respiratory protection author ized per U.S. OSHA's requirement in 29 CFR §1910.134, or applicable U.S. state regulations, or the appropriate standards of Canada, its provinces, E.C. member states, or Australia. EYE PROTECTION: Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to U.S. OSHA 29 CFR §1910.133, Canadian standards, or the European Standard EN166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to e yes. PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur during use o f this product, wear gloves for routine indus trial use. If necessary, refer t o U.S. OSHA 29 CFR §1910.138, the appropriate standards of Can ada, of the E.C. member states. OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances of use and handling. If necessary, refer to appropriate standards of Canada, the E.C. member states, or U.S. OSHA. An eyewash station and a safety shower are recommended. Hig h temperature processing equipment should be well ventilated. Section 9 - Physical and Chemical Properties APPEARANCE: Fine pink p igmented powder. ODOR: Faint odor in bulk. pH: NA ODOR THRESHOLD: ND BOILING POINT: NA FREEZING POINT: NA VISCOSITY: NA SPECIFIC GRAVITY (H 2 O=1): ND VAPOR PRESSURE: NA PERCENT VOLATILE W/W%: NA VAPOR DENSITY ( AIR=1): NA EVAPORATION RATE (BuAc =1): NA SOLUBILITY IN WATER: Insoluble. COEFFICIENT OF WATER/OIL DISTRIBUTION: ND Section 10 - Stability and Reactivity CONDITIONS TO AVOID: Heating above 240  C, 464  F. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned. HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X STABILITY: UNSTABLE: STABLE: X

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