SDS PDF 2017 Duraglaze Thinner Liquid

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3. 3 of 8 Duraglaze Thinner Liquid Inhalation: May cause drowsiness or dizziness. Ey es: Causes serious eye irritation. Section 5 - Fire Fighting Measures Suitable Extinguishing Media: Recommended extinguishing media; alcohol resistant foam, CO 2 , powder, water spray. Do not use water jet. Unsuitable Extinguishing Media: Water spra y or water stream may not be effective. Specific Hazards Arising from the Chemical: Hazardous decomposition: None at ambient temperature. Keep away from heat/sparks/open flames/hot surfaces – No smoking. Keep cool. Ground/bond container and receiving e quipment. Use explosion - proof electrical / ventilating/ light / equipment. Use only non - sparking tools. Take precautionary measures against static discharge. Avoid breathing dust / fume/ gas/ mist/ vapors / spray. Protective Equipment and Precautions for Firefighters: Wear self - contained breathing apparatus (pressure - demand, MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to cool containers. Do not use water on open flame. Dike fire area gently with fine, dry sand to extinguish fire. Do not use halogenated hydrocarbon extinguishing agents. Special Fire Fighting Procedures: Vapors can travel to a source of ignition and flash back. Material can form explosive vapors with air. Avoid contact with water. ERG Guide No. 128 Section 6 - Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions: Before cleaning any spill or leak, individuals must wear appropriate Personal protective Equipment that is specified is section 8. Deny entry to all unprotected individuals. Remove any contaminated clothing and wash thoroughly before reuse. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. Environmental Precautions: Extinguish all ignition sources. Keep spills and cleaning runsoffs out of municipal sewers and open bodies of water. Methods and Material for Containment and Cleaning UP Methods for Containment : Prevent further leakage or spillage if safe to do so. Dike and contain spill with inert material (e.g. sand or earth). Methods for Cleaning Up: Ma ximize ventilation (open doors and windows) and secure all sources of ignition. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water. Eliminate all ignition sources. Evacuate personnel to safe areas. Ventilate the area. Floor may be slippery, use caution. Soak up with inert absorbent material (paper towel, sand, silica gel, sawdust). Avoid breathing vapor. Wear MSHA/NIOSH approved respirator. Note: Spil ls on porous surfaces can contaminate ground water. Normal Disposal. Waste Classification: Methyl Ethyl Ketone (78 - 93 - 3), 40 CFR 261.20 - 24. For discard, this is classified as a hazardous waste with the characteristic of ignitability and toxicity. RCRA #D001. Reportable quantity is 100 lbs. (40 CFR 302) Incinerate liquid and contaminated solids in accordance with

8. 8 of 8 Duraglaze Thinner Liquid Section 16 - Additional Information Hazardous Material Information System (HMIS) Rating HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 2 PERSONAL PROTECTION B National Fire Protection Association (NFPA) HMIS & NFPA Hazard Rating HEALTH 2 FLAMMABILITY 3 INSTABILITY 2 HMIS & NFPA Hazard Rating * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH B = Gloves and Safety Glasses or Chemical Goggles. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no li ability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Reliance Dental Mfg. Co. be liable for any claims, losses, or damages of any third p arty or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if user has been advised of the possibility of such damages. Revised October 2, 2017

2. 2 of 8 Duraglaze Thinner Liquid S ection 3 – Composition / Information on Ingredient This product contains the following substances that present a hazard within the meaning of th e relevant State and Federal Hazardous Substances regulations. Ingredient.Chemical Designations Weight % GHS Classification Notes Butanone – CAS No. 0000078 - 93 - 3 70 - 85 Flam. Liquid 2 - H225; Eye Irrit.2 - H319; STOT SE 3:H336 (1) (2) In accordance with paragraph (i) of § 1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit [3] PBT - substance or vPvB – substance *The full texts of the phrases are shown in Section 16 Section 4 - First Aid Measures General Advice: Provide the SDS to medical personnel for treatment Inhalation: Remove victim to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious please in the recovery position and obtain i mmediate medical attention. Give nothing by mouth. Eye Contact: If product gets in the eyes, flush with lukewarm water for at least 15 minutes. If irritation occurs, contact a physician. Skin Contact: Rinse thoroughly with lukewarm water, followed by a tho rough washing of the affected area with soap and water. If irritation, redness or swelling persists, contact a physician immediately. Clothing: Remove contaminated clothing, wash thoroughly before reuse. Ingestion: If ingested, do not induce v omiting. Get medical attention immediately. Keep at rest. Most important symptoms and effects, both acute and delayed Overview INHALATION/INGESTION: Solvent vapor or mist can cause headache, nausea, dizziness, incoordination, stupor, irritation of n ose, throat, and lungs. Irritation of digestive tract. Nervous system ddepression (fatigue, drowsiness, dizziness). SKIN/EYES: Burning, tearing, redness and swelling of eyes, transient corneal injury, drying and cracking of skin. Medical Conditions - Generally Aggravated by exposure: pre - existing skin disorders, respiration, liver, kidney & Wilson’s disease. Exposure to solvent vapor concentrations from the component solvents in excess of stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidney, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakn ess, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non - allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details.

4. 4 of 8 Duraglaze Thinner Liquid local, state and federal regulations. (See 40 CFR 268). For small quantity spills, allow solvent in pap er towel to evaporate in well ventilated areas or outdoors (preferred). Contaminated Packaging: Empty containers should be taken for local recycling or waste disposal. Section 7 - Handling and Storage Precautions for safe Handling Advice on Safe Handling: Store in accordance with the National Fire Protection Association’s publications NFPA 30, Flammable and Combustible Liquids Code, 29 CFR1910.106 applies to the handling, storage, and use of flammable and combustible liq uids. See section 2 for further details (Prevention). Conditions for Safe Storage, Including any Incompatibilities Storage Conditions: Handle containers carefully to prevent damage and spillage. Store container in a cool, dry location, away from direct sunlight, heat, s parks, flame, other light sources, or sources of intense heat. Store in accordance with National Fire Protection Association recommendations. P roduct residue may rema in in empty containers. Incompatible Materials: Water, acids, alkalis, chlorinated solvents. Section 8 - Exposure Controls, Personal Protection Exposure Chemical Name ACGIH NIOSH OSHA Butananone 0000078 - 93 - 3 50 ppm TWA; 100 ppm STEL 200 ppm TWA; 590 mg/m3 TWA 3 00 ppm (885 mg/m3) ST 2 00 ppm TWA; 590 mg/m3 TWA Carcinogen Data Chemical Name OSHA NTP IARC Butananone 0000078 - 93 - 3 Select Carcinogen: No Known: No Suspected: No Group 1: No Group 2a: No Group 2b: No Group 3: No Group 4: No Personnel Protective Equipment (PPE) Respiratory Protection: If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. Eye/Face Protection: Chemical - resistant goggles. Skin and Body Protection Use a chemical - resistant apron or other impervious clothing, and rubber boots if necessary, to avoid contaminating regular clothing and shoes and to prevent skin contact. Chemical resistaant gloves. Engineering Controls: Provide adequate ventilation. Where reasonable practicable this hould be achieved by the use of local exhaust ventiliation and good general extraction. General Hygiene Condsiderations: H andle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. An eyewash station and a safety shower are recommended. Food, beverages, and tobacco

7. 7 of 8 Duraglaze Thinner Liquid Section 14 - Transport Information DOT (Domestic Surface T ansportation) IMO / IMDG (Ocean Transportation) ICAO / IATA UN Number UN1993 UN1993 UN1993 UN Proper Shipping Name Un1993, Flammable Liquids, n.o.s. (Ethyl Methyl Ketone) Flammable Liquid, n.o.s. (Ethyl Mthyl Ketone) Flammable Liquid, n.o.s. (Ethyl Methyl Ketone) Transport Hazard Class DOT Hazard Class: 3 IMDG: 3 Sub Class: Not A pplicable Air Class: 3 Packing Group ll ll ll Environmental Hazard Marine Pollutant: No Special precautions for user: No further information. Section 15 - Regulatory Information Regulatory Overview: The regulatory data in Section 15 is not intended to be all - inclusive, only selected reg ulations are represented. Toxic Substance All components of this material are either listed or exempt from listing Control Act (TSCA): on the TSCA Inventory. WHMIS Classification: B2 D2B US EPA Tier II Hazards: Fire: Yes Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 311/312 Chemicals and RQs (LBS): Butanone (5,000.00) EPCRA 302 Extremely hazardous: To the best of our knowledge, there are no che micals at levels which require reporting under this statute. EPCRA 313 Toxic Chemicals: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Carcinogens (.0.0%): To th e best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Developmental Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting und er this statute. Proposition 65 – Female Repro Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 – Male Repro Toxins (.0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. New Jersey RTK Substances (>1%): Butanone Pennsylvania RTK Substances (>1%): Butanone Country Regulation All Components Listed EINECS Yes SARA Hazard categories Yes TSCA Inventory Yes

1. 1 of 8 Duraglaze Thinner Liquid Safety Data Sheet Section 1 - Chemical Product and Company Identification Product Name: Duraglaze Thinner Company Identification: Reliance Dental Mfg., LLC. 5805 W. 117 th Place Alsip, IL 60803 For Product Information, call: 708 - 597 - 6694 For Medical Information, call: 800 - 535 - 5053 Section 2 - Hazards Identification Classification of the substance or mixture Hazard Class – Phy sical, Health, environmental Category Flammable Liquid 2 Eye Irritation 2 Specific Target Organ Toxicity - Single Exposure 3 Label Elements - Pictograms, Signal Word, Hazard Statements, Precautionary Statements, & Supplemental Information Signal Word: Danger Hazard Statements Precautionary Statements – Prevention, Response, Disposal H225 Highly flammable liquid and vapor H319 May cause serious eye irritation P210 Keep away from heat/sparks/open flames/hot surfaces - No Smoking H336 May cause drowsiness and dizziness P23 5 Keep cool P240 Ground and bond container and receiving equipment P241 Use explosion - proof electrical/ventilating/light/.../equipment P242 Use only non - sparking tools P243 Take precautionary measures against static discharge P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash hands and exposed skin thoroughly after handling P271 Use only outdoors or in a well - ventilated area P280 Wear protective gloves/protective clothing/eye protection/face protection P303+P361 IF ON SKIN - Wash (or hair), remove / take off immediately all +P353 contanminated clothing. Rinse skin with water with soap and water P304+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breath ing; call a POISON CENTER or doctor/physician if you feel unwell. P 305+P351 IF IN EYES: Rinse continuously with water for several +P338 minutes. Remove contact len ses if present and easy to do continue rinsing. P337+313 If eye irritation persists: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable or breathing. P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction. [Storage]: P403+2 33 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations.

5. 5 of 8 Duraglaze Thinner Liquid products should not be carried, stored or consumed where this material is in use. Wash hands thoroughly before eating, drinking, or smoking. Other Work Practices See section 2 for further details – [Prevention] Section 9 - Physical and Chemical Properties Appearance: Clear , colorless Odor: S weet /sharp odor PH: Not measured Initial boiling point and boiling range: 80 C/ 176 F initial Evaporation Rate (Ether=1): >1.0 (Butyl Acetate=1) Upper/Lower Flammablility or Lower Explosive Limit: 1.8 Explosive Limits: Upper Explosive Limit:11.5 Specific Gravity: 0.9 5 - 1.0 (H2O = 1) Partition Coefficient n - octanol/water (Log Kow) : Not measured Decomposition temperature: Not measured Physical State: Liquid Odor Threshold: Not determined Melting Point/ Freezing point: - 86 C/ - 123 F initial Flash Point: - 4 C /25 F ( SF CC) Flammability (solid,gas): Not applicable Vapor pressure (Pa): 80 mm Hg @20C /68F Vapor Density : >1.0 Solubility in Water: Slight Auto - ignition Temp . : 516 C/961 F Viscosity (cSt): 400 cPs max Other information: No other relevant information. Section 10 - Stability and Reactivity Reactivity: Hazardous Polymerization will not occur. Chemical Stability: Stable under normal circumstances. Possibility of Hazardous Reactions: No Data Available. Conditions to Avoid: Avoid contact with water, mineral acids, chlorinated solvents. Incompatible Materials: Water, acids, alkalis, chlorinated solvents. Hazardous Decomposition Products: None at ambient temperature. Section 11 - Toxicological Information Acute toxicity : Ex posure to solvent vapor concent rations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effe cts on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparat ion may cause removal of natural fat from the skin resulting in dryness, irritation and possible non - allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.

6. 6 of 8 Duraglaze Thinner Liquid Ingredient Oral LD50, mg/kg Skin LD 50, mg/kg Inhalation Vapor LC50, mg/L/ 4hr Inhalation Dust/Mist LC50, mg/L/4hr Inhalation Gas LC50, ppm Butanone 78 - 93 - 3 2 .737.00, Rat Category : 5 6,480.00, Rabbit Category: NA 32.00, Mouse Category: NA No Data Available No Data Available Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product’s ATE (Acute toxicity Estimate). Classification Category Hazard Description Acute Toxicity (Oral) --- Not Applicable Acute Toxicity (Dermal) --- Not Applicable Acute Toxicity (Inhalation) --- Not Applicable Skin Corrosion/irritation --- Not Applicable Serious Eye Damage/Irritation 2 Causes serious eye irritation Respiratory Sensitization --- Not Applicable Skin Sensitization --- Not Applicable Germ Cell Mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive Toxicity --- Not Applicable STOT – Single Exposure 3 May cause drowsiness or dizziness STOT – Single Exposure --- Not Applicable STOT – repeated exposure --- Not Applicable Aspiration Hazard --- Not Applicable Section 12 - Ecological Information Toxicity: No additional information provided for this product. See Section 3 for Chemical specific data. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 Crustacea, mg/l ErC50 Algae, mg/l Butanone – (78 - 93 - 3) 400.00, Cyprinodon Variegatus 520.00 Daphnia Magna 500.00 (96hr), Skeletonema Costatum Persistence and Degradability: There is no data available on the preparation itself. Bioaccumulative Potential: Not measured. Mobility in Soil: No data available. Results of PBT & vPvB Assessment: This product contains no PBT/vPvB chemicals. Other adverse effects: No data available. Section 13 - Disposal Considerations Waste Treatment Methods Disposal of Wastes : Observe all Federal, State and Local regulations when disposing of this substance.

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