SDS PDF 2017 Duralay Temporary C&B Powder-Shades

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5. 5 of 6 Duralay Temporary C&B Powder - Shades Section 11 - Toxicological Information MIXTURE TOXICITY Component Toxicity Routes of Exposure: Inhalation, Eye Contact, and Ingestion Target Organs: Eyes, Lungs, Central Nervous System, Reproductive System, Skin, Peripheral Nervous System, and Respiratory System Effects of Overexposure: Inhalation: Overexposure by inhalation of titanium dioxide may include mild and temporary upper respiratory irritation with cough and shortness of breath. Skin Contact: No data found. Eye Contact: No data found. Ingestion: No data found. Product Components Listed as Carcinogenic CAS Number Description %Weight Carcinogen Rating 13463 - 67 - 7 Titanium Dioxide (CI 77891) 0.1 TO 1.0 % Titanium Dioxide (CI 77891): NIOSH - potential occupational carcinogen IARC - Possible human carcinogen OSHA - Listed Section 12 - Ecological Information Component Ecotoxicity Diethyl Phlthalate: 96Hr LC50 Pimphales promelas : 17 mg/L (flow - through): 96 Hr LC50 Pimephales promelas: 16.8 mg/L (static): 96 Hr LC50 Lepomis macrochinus : 22 mg/L (flow - through): 96 Hr LC50 Lepomis macrochirus: 16.7 mg/L (static): 96 Hr LC50 Oncorhynchus mykiss: 12 mg/L (flow - through) 48 Hr EC50 Daphnia magna: 36 - 74 mg/L; 48 Hr EC50 Daphnia magna: 86 mg/L (static) 72 Hr EC50 Desmodesmus subspicatus: 23 mg/L; 72 Hr EC50 Desmodesmus subspicatus; 23 mg/L )static); 96 Hr EC50 Desmordesmus subspicatus: 21 mg/L; 96 Hr EC50 D esmodesmus subspicatus: 21 mg/L (static); 72 Hr EC50 Pseudokirchneriella subcapitate: 42 – 255 mg/L; 96 Hr EC50 Pseudokirchneriella subcapitate: 2.11 - 4.29 mg/L (static) Section 13 - Disposal Considerations WASTE DISPOSAL METHOD Disposal of Wastes: Dispose of properly in accordance with Federal, State, and Local regulations. It is the responsibility of the generator to determine at the time of disposal whether the produ c t meets the criteria of a hazardous waste. Comply with all applicable federal, state a nd local regulations. Waste disposal options include landfilling solids at permitted sites. Incinerate in a chemical incinerator equipped with an afterburner and scrub ber. Use registered transporters. Contaminated Packaging : Reuse of empty drums or containers is not recommended. Employees should be advised of the potential hazards, due to residual flammable material, associated with empty containers. Dispose of all e mpty containers properly, in accordance with Federal, State and Local regulations.

6. 6 of 6 Duralay Temporary C&B Powder - Shades Section 14 - Transport Information Agency Proper Shipping Name UN Number Packing Group Hazard Class DOT Not Regulated, Polymer, NOS IATA Not Regulated, Polymer, NOS IMDG Not Regulated, Polymer, NOS Section 15 - Regulatory Information State of California Safe drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains the following chemicals which are listed by the State of Califonia as carcinogenic or a reproductive toxin: 13463 - 67 - 7 Titanium Dioxide (CI 77891) 0.1 to 1.0% Carcinogen SARA 313 Benzoyl Peroxide 94 - 36 - 0 US State Right - to - know Regulations - None Country Regulations All Components Listed EINECS Yes SARA Hazard categories No TSCA Inventory Yes Section 16 - Additional Information HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTIVE EQUIPMENT: B NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 HMIS & NFPA Hazard Rating *= Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH B = Gloves and Safety Glasses or Chemical Goggles. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the dat e of its publication. The information given is designed only as a guidance for safe handling, use, process, storage, transportatio n, disposal and release and is not considered a warranty or quality specification. This information relates only to the specific materia l designated and may not be valid for such materials used in combination with any other materials on in any process, un less specified in the text. Revised October 2, 2017

3. 3 of 6 Duralay Temporary C&B Powder - Shades Section 6 - Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Before cleaning any spill or leak, individuals must wear appropriate Personal Protective Equipment that is specified in section 8. Keep airborne particulates at a minimum when cleaning up spills. Deny entry to all unprotected individuals. Remo ve any contaminated clothing and wash thoroughly before reuse. Evironmental Precautions Extinguish all ignition sources. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water. US regulations (CERCLA) require reporti ng spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800)424 - 8802. Methods and Material for Containment and Cleaning Up Methods for Containmen t Prevent further leakage or spillage if safe to do so. Dike and contain spill with inert material (e.g. sand or earth). May contaminate water supply. Methods for Cleaning U p Maximize ventilation (open doors and windows) and secure all sources o f ignition. Use good, local ventilation with a minimum capture velocity of 100 ft/min (30 m/min) at point of product release. Place into appropriate closed container(s) for disposal in accordance with local, state and federal regulations. Wash all affected areas with plenty of war m water and soap. Not a RCRA Hazardous waste. Section 7 - Handling and Storage PRECAUTIONS FOR HANDLING Advice on Safe handling: Use in well ventilated areas. Avoid contact with skin, eyes and clothing. Avoid breathing dust. Use good personal hygiene and housekeeping. Avoid prolonged contact with the product. Use in a well - ventilated location (e.g., local exha use ventilation, fans). After use, wash hands and exposed skin with soap and water. Do not eat, drink or smoke while handling product. Conditions for Sate Storage, Including any Incompatibilities Storage conditions : Store containers in a co ol, dry location, away from direct sunlight, heat, sparks, flame, o ther light sources, or sources of intense heat. The temperature should remain at or under 72°F (22°C) at all times. Storing above recommended temperature will cause produ ct performance issues. Store in accordance with National Fire Protection Asso ciation recommendations. Observe all label precautions until the container is cleaned, reconditioned or destroyed. Incompatible Materials : Strong oxidizers, strong ox idizing agents Section 8 - Exposure Controls, Personal Protection Chemical name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits Polymethyl Methacrylate 9011 - 14 - 7 Diethyl Phthalate 84 - 66 - 2 5 mg/m3 TWA NIOSH: 5 mg/m3 TWA Benzoyl Peroxide 94 - 36 - 0 5 mg/m3 TWA 5 mg/m3 TWA NIOSH: 5 mg/m3 TWA Titaniuim Dioxide (CI77891 13463 - 67 - 7 15 mg/m3 TWA (total dust) 10 mg/m3 TWA

4. 4 of 6 Duralay Temporary C&B Powder - Shades Engineering Controls Use local explosion - proof ventilation that is adequate to keep employee exposure to airborne concentrations below exposure limits. Please refer to the ACGIH document, Indust rial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personnel Protective Equipment (PPE) Respiratory Pro tection A respirator should be worn whenever workplace conditions warrant use of a respirator. If dust conditions are present, a N95 respirator dust mask is required. None required if airborne concentrations are maintained below any exposure limit that may be listed above. If necessary, use only respiratory protection authorized per U.S. OSHA’s requirement in 29 CFR §1910.134 or other appropriate governing standard. Eye/Face Protection Wear safety glass es, c h emical goggles when splashing is possible, when dealing with this materials. If necessary, refer to 29 CFR §1910.133, or other appropriate governing standard. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes. Skin and Body Protection Complete suit protecting against chemicals, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove ’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accor dance with applicable laws and good laboratory practices. Wash and dry hands. Full Contact: Splash Contact: Material: Nitrile rubber Material: Nitrile rubber Minimum Layer thickness: 0.4 mm Minimum Layer thickness: 0.11 mm Break through time: 480 min. Break through time: 120 min. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. An eyewash station and a safety shower are recommended. Food, beverages, and tobacco products should not be carried, stored or consumed where this material is in use. Wash hands thoroughly before eating, drinking, or smoking. Section 9 - Physical and Chemical Properties APPEARANCE: Fine white powder. ODOR: Faint odor in bulk. FLASH POINT: 57 7 °F, 30 3 °C FLAMMABLE LIMIT (AIR VOLUME %) 0% EVAPORATION RATE No data available. BOILING RANGE (LOW - HIGH) 295°C SPECIFIC GRAVITY: 0.00 Section 10 - Stability and Reactivit y MATERIAL STABILITY Stable INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned. POSSIBILITY OF HAZARDOUS REACTI0NS Hazardous polymerization will not occur.

1. 1 of 6 Duralay Temporary C&B Powder - Shades Safety Data Sheet Section 1 - Chemical Product and Company Identification Product Name: Duralay Temporary C & B Powder - Shades Company Identification: Reliance Dental Mfg., LLC. 5805 W. 117 th Place Alsip, IL 60803 For Product Information, call: 708 - 597 - 6694 For Medical Information, call: 800 - 535 - 5053 Section 2 - Hazards Identification Classification of the substance or mixture Hazard Class – Physical, Health, Environmental Category Eye Damage/Irritation 2A Skin sensitizer 1 Repoductive Toxicity 2 Aquatic Toxicity A3 OSHA Defined Hazards: Combustible dust, may form combustible dust concentrations in air, explosion hazard Label elements – Pictograms, Signal Word, Hazard Statements, Precautionary Statements & Supplemen tal Information Signal Word Warning Hazards Statements Precautionary Statements - Prevention, Response & Disposal H317 May cause an allergic skin reaction P201 Obtain special instructions before use H320 Causes eye irritation P202 Do not handle until all safety precautions have been H361 Suspected of damaging fertility of the read and understood u nborn child P240 Ground and bond container and receiving equipment H402 Harmful to aquatic life P261 Avoid breathing dust/fu me/gas/mist/vapors/spray P264 Wash hands and exposed skin thoroughly after handling P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protec tion/face protection P281 Use personal protective equipment as required P321 Specific treatment (see...on this label) P363 Wash contaminated clothing before reuse P302+P352 IF ON SKIN: Wash with soap and water P305+P351 IF IN EYES: Rinse continuously with water for several +P338 minutes. Remove contact lenses if present and easy to do – continue rinsing P308+P313 IF exposed or concerned: Get medical advice/attention P333+P313 If skin irritation or a rash occurs: Get medical advice/ treatment P337+P313 Get medical advice/attention P405 Store locked up P501 Dispose of contents/container to an authorized disposal facility

2. 2 of 6 Duralay Temporary C&B Powder - Shades Section 3 - Composition, Information on Ingredients Item Chemical Name CAS # WT/WT% GHS Ratings 01 Polymethyl Methacrylate 9011 - 14 - 7 8 0 - 9 0 Eye damage/Irritation 2B(H320) 02 Diethyl Phthalate 84 - 66 - 2 1 0 – 20 Eye damage/Irritation 2B(H320) Reproductive Toxicity 2 (H361) Aquatic Toxicity A3 (H402) 03 Benzoyl Peroxide 94 - 36 - 0 1 – 5 Eye damage/Irritation 2A(H319) Skin Sensitizer 1 (H317) 04 Titanium Dioxide (CI 77891) 13463 - 67 - 7 0 – 1 SECTION 4 - FIRST AID RES Section 4 - First Aid Measures General advice Provide the SDS to medical personnel for treatment. Inhalation: Remove victim to fresh air. Seek immediate medical attention. Eye Contact: If product gets in the eyes, flush with lukewarm water for at least 15 minutes. If irritation occurs, contact a physician. Skin Contact: Rinse thoroughly with lukewarm water, followed by a thorough washing of the affected area with soap and w ater. If irritation, redness or swelling persists, contact a physician immediately. Clothing: Remove contaminated clothing, wash thoroughly before reuse. Ingestion: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or milk. Never give anything by mouth to an unconscious person. Provide an estima te of the time at which the material was ingested and the amount of the substance that was swallowed. Get medical attention immediately. Section 5 - Fire Fighting Measures Suitable Extinguishing Media: Water, Chemical (alcohol - resistant) foam, dry chemical, or carbon dioxide. Unsuitable Extinguishing Media: Water may not be effective in extinguishing this fire. Specific Hazards Arising from the Chemical: Polymers are combustible dusts, c are should be taken to avoid creating explosive concentrations in the air. Follow grounding and bonding procedures. Special Fire Fighting Procedures: Avoid extinguishing methods, which may generate dust clouds. Water stream can dis perse dust into air producing a fire hazard and possible explosion hazard if exposed to ignition source. Firefighters should wear self - contained breathing apparatus. Protective Equipment and Precautions for Firefighters: Polymer dust is c ombustible. The explosive limits of the polymer particles suspended in air are approximately those of coal dust. Polymers are sensitive to static discharge, follow grounding and bounding procedures. Polymers are not sensitive to mec hanical impacts. Unsuitable Extinguishing Media

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